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| Personal Protective
Equipments / Respiratory
Protection |
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MSA Respirators cartridges and filters are certified by National
Instituted for safety & health (NIOSH). We offer most
of the filters, cartridges and supplied air system you need
to meet standards & regulations for recommended respiratory
protections.
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Disposable Respirators
& Masks |
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Half face mask
Respirators (Cartridge type) |
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Full face mask
Respirators (Cartridge type) |
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Gas mask with canisters. |
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Powered Air Purifying Respirators
(PAPR) |
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Supplied air Respirators |
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Air line Respirators |
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"Factors that can Reduce
Cartridge Service Life"
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Exertion Level |
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Cartridge Variability |
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Temperature |
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Humidity |
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Multiple Contaminants |
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Worker Exertion Level
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"A worker breathing twice as fast
as another will draw twice the amount of contaminant through
the respirator cartridge".
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The service life of a cartridge or canister
respirator depends upon the total amount of contaminant captured
by the absorbent. The total amount of captured contaminant
is directly related to the work rate or breathing rate; i.e.,
a worker breathing twice as fast as another will draw twice
the amount of contaminant through the respirator cartridge.
Most cartridge studies have used a breathing rate, 50-60 liters
per minute, that approximates a high end of moderate workrate.
For workrates that exceed this level (e.g., heavy shoveling,
running) you may need to apply or take into account a correction
factor when determining a service life.
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Respirator Cartridge Variability
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"Some cartridges contain more activated
charcoal than others"
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The service life of a respirator cartridge
is directly related to the amount of active material in the
cartridge. For instance, most dual cartridge organic vapor
respirators contain between 35-50 grams of activated charcoal
in each cartridge. If the specific cartridge being evaluated
can be reproducibly determined to have a certain amount of
active material, then modifications to the service life may
be justified. You can obtain information on cartridge specifications
from manufacturers.
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Temperature
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"The hotter it is, the shorter the
service life"
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High temperatures can adversely affect the
adsorptive capacity of respirator cartridges and canisters.
The high temperature may act by thermally loosening the attractive
forces that make adsorption happen or may act in concert with
humidity by increasing the moisture carrying capacity of air.
This latter mechanism may represent the greatest likely effect
on service lives of cartridges. Temperature effects alone
have been reported to reduce the service life 1-10% for every
10 degrees Celsius rise depending
on the specific solvent (Nelson, et. al., 1976). Corrections
to cartridge estimated service life for this effect alone
are probably not necessary under normal working temperatures
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Relative Humidity
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"Water vapor will compete with the
organic vapors for active sites on the adsorbent"
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Relative Humidity is a measure of the amount
of water vapor the air will hold at a specified temperature
and is expressed in percentage values. Since warmer air will
hold more water than colder air, the same relative humidity
at a higher temperature represents a significantly greater
amount of moisture. High relative humidity is a significant
negative factor in the capacity of organic vapor cartridges
since the large quantity of water vapor will compete with
the organic vapors for active sites on the adsorbent. Most
of the laboratory work determining adsorbent capacity has
been performed at a low relative humidity of 50% at approximately
70 degrees F.
If the actual use of the organic vapor respirators
will take place in a significantly more humid environment,
then you may need to apply or take into account a safety factor
when determining a service life. The exact magnitude of the
humidity effect is complex, dependent in part upon chemical
characteristics and concentrations of both the contaminant
and the water vapor. Based upon relatively few studies, a
reduction by a factor of 2 in the cartridge service life originally
estimated based upon 50 % relative humidity, may be made when
the relative humidity reaches 65%. If the relative humidity
exceeds 85%, you should consider experimental testing or another
method to more specifically determine the service life. Mathematical
modeling may be an appropriate, albeit complex, approach to
predict the effect of humidity at various chemical concentrations.
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Multiple Contaminants
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"Predictions should be derived from
the least well adsorbed compound"
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Multiple contaminants introduce a great deal
of variability into the prediction of service life for respirator
cartridges. Much of the laboratory testing and the mathematical
models have utilized a single contaminant to determine service
lives. Only a limited number of multiple contaminant situations
have been studied and reported in the literature (e.g. Yoon,
1996; Jonas et. al., 1986). Cartridge service life for mixtures
of compounds with significantly different chemical characteristics
is probably best determined by experimental methods. Predictions
based upon models without experimental data should probably
be very conservative and ascribe the service life derived
from the least well adsorbed compound to the total mixture
concentration in terms of parts per million. The displacement
of a less well adsorbed compound by a more highly adsorbed
one may alter the actual service life from the estimated one
in some cases.
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